3D Printing of Patterned Membranes

A new type of 3D printing developed by researchers at Penn State will make it possible for the first time to rapidly prototype and test polymer membranes that are patterned for improved performance.

Ion exchange membranes are used in many types of energy applications, such as fuel cells and certain batteries, as well as in water purification, desalination, removal of heavy metals and food processing. Most ion exchange membranes are thin, flat sheets similar to the plastic wrap in your kitchen drawer. However, recent work has shown that by creating 3D patterns on top of the 2D membrane surface, interesting hydrodynamic properties emerge that can improve ion transport or mitigate fouling, a serious problem in many membrane applications.

Currently, making these patterned membranes, also called profiled membranes, involves a laborious process of etching a silicon mold with the desired pattern, pouring in the polymer and waiting until it hardens. The process is both time-consuming and expensive, and results in a single pattern type.

“We thought if we could use 3D printing to fabricate our custom-synthesized ion exchange membranes, we could make any sort of pattern and we could make it quickly,” says Michael Hickner, associate professor of materials science and engineering at Penn State.

In a paper published online today in the American Chemical Society’s journal ACS Applied Materials and Interfaces, Hickner’s team describes the development of a custom 3D photolithographic printing process similar in concept to a current 3D process called stereolithography. The team developed a photocurable mixture of ionic polymers and exposed the mixture under a light projector to harden the base layer. They then added more polymer to the base layer and projected a pattern on the new material to selectively harden the surface. The surface pattern increases the conductivity of the membrane by as much as a factor of two or three.

“Membranes act like a resistor in a battery or fuel cell,” says Hickner. “If you can lower the resistance by a factor of two or three, you’ve really got something useful.”

Lead author and a Ph.D. candidate in materials science and engineering, Jiho Seo, added, “While surface patterned membranes have been studied previously, this is the first 3D printed example of these structures and the first model that really explains the resistance decrease in a quantitative way. A simple parallel resistance model describes the effect of the pattern on lowering the resistance of these new membranes. This insight gives us a design tool to continue to innovate and create new patterns for further improvements along with changing the intrinsic chemistry of the material.”

The team will continue to optimize the geometry and chemistry of the membranes they print, as well as learn to print new materials, both for membranes and beyond, that have never been printed heretofore.

“We want to bridge the fundamental chemistry and materials science that we do with the engineering and rapid design iterations that the 3D printing industry is really good at,” Hickner concludes.

In addition to Seo and Hickner, Douglas Kushner, Ph.D. student in materials science and engineering, contributed to the paper titled “3D Printing of Micro-patterned Anion Exchange Membranes.”

Support for the photolithography system was provided by Penn State Department of Materials Science and Engineering. The Materials Research Institute and the Penn State Institutes of Energy and the Environment provided infrastructure support.